Güncel Gönderiler: Fen Fakültesi
Toplam kayıt 2379, listelenen: 361-380
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Structural studies of water-soluble ß-brominated manganese porphyrins: Stabilities of MnTDCSPPBr8 and MnTSPPBr8 as homogeneous and supported reagents toward hydrogen peroxide and sodium hypochlorite
(2001)This article describes the structural stabilities of [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(2,6-dichloro-3- sulfonatophenyl)porphinato]manganese(III) X (where X = H2O and/or OH-, depending on pH) (MnTDCSPPBr8) ... -
Protonation, tautomerization and valence tautomerization of selected imidazo[4,5-f]quinolines. A theoretical study of gas and liquid basicity of imidazo[4,5-f]quinolines
(1993)The theoretical calculations on imidazo[4,5-f] quinolines has shown that the first protonation takes place at the pyridine, nitrogen atom rather than at the imidazole nitrogen atom. The preferred tautomeric form was found ... -
Latex supported manganese (III) porphyrin catalysts for oxidations of alkenes by hydrogen peroxide and tert-butyl hydroperoxide in the aqueous medium
(1996)Cationic polymer latexes were prepared by emulsion copolymerization of vinylbenzyl chloride and divinylbenzene followed by quaternization with trimethylamine and used as catalyst supports for 5,10,15,20-tetrakis(2, ... -
Performance of dye-affinity beads for aluminium removal in magnetically stabilized fluidized bed
(2004)Background: Aluminum has recently been recognized as a causative agent in dialysis encephalopathy, osteodystrophy, and microcytic anemia occurring in patients with chronic renal failure who undergo long-term hemodialysis. ... -
Photocatalytic oxidation of nitrobenzene and phenylamine: Pathways and kinetics
(John Wiley & Sons Inc, 2007)The oxidation of nitrobenzene and phenylamine has been carried out by heterogeneous photocatalysis in aqueous suspensions of commercial TiO2. The photoreactivity results indicate that two reaction pathways occur in parallel ... -
Photocatalytic selective oxidation of 4-methoxybenzyl alcohol to aldehyde in aqueous suspension of home-prepared titanium dioxide catalyst
(Wiley-V C H Verlag GMBH, 2007)The photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde (PAA) was performed in water with organic-free suspensions of home-prepared and commercial titanium dioxide (TiO2) catalysts. The nanostructured ... -
Kinetics of 4-Methoxybenzyl Alcohol Oxidation in Aqueous Solution in a Fixed Bed Photocatalytic Reactor
(American Chemical Society, 2010)The photocatalytic oxidation of 4-methoxybenzyl alcohol in water was performed in a fixed bed continuous annular reactor by using a home-prepared TiO2 catalyst supported on Pyrex glass beads. The investigation was aimed ... -
Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home prepared titanium dioxide 2. Intrinsic and surface features of catalysts
(Elsevier Science BV, 2008)In this paper some intrinsic electronic properties of home prepared (HP) TiO2 Catalysts were investigated by diffuse reflectance spectroscopy and quasi-Fermi level measurements. These powders were used for carrying out the ... -
Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home-prepared titanium dioxide 1. Selectivity enhancement by aliphatic alcohols
(Elsevier Science BV, 2008)Oxygenated aqueous suspensions of home-prepared (HP) and commercial TiO2 catalysts were used in a batch photoreactor for carrying out the oxidation of benzyl alcohol (BA) and 4-methoxybenzyl alcohol (MBA) under different ... -
Self-assembled titania-silica-sepiolite based nanocomposites for water decontamination
(Royal Soc Chemistry, 2009)This work describes the preparation of microchannel structured monolithic pieces by the "ice-segregation induced self-assembly'' (ISISA) process. The monoliths exhibit a hierarchical structure composed of homogeneously ... -
Home-prepared anatase, rutile, and brookite TiO2 for selective photocatalytic oxidation of 4-methoxybenzyl alcohol in water: reactivity and ATR-FTIR study
(Royal Soc Chemistry, 2009)TiO2 catalysts of anatase, rutile and brookite phase were prepared at low temperature and tested for carrying out the photocatalytic partial oxidation of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde (p-anisaldehyde) ... -
A quantitative method of photoadsorption determination for irradiated catalyst in liquid-solid system
(Elsevier Science BV, 2009)A method for determining the amount of substrate adsorbed onto the catalyst surface in liquid-solid photocatalytic system under reaction conditions (photoadsorption) is proposed. The method has been applied to the ... -
Environmentally Friendly Photocatalytic Oxidation of Aromatic Alcohol to Aldehyde in Aqueous Suspension of Brookite TiO(2)
(Springer, 2008)Photocatalytic oxidation of 4-methoxybenzyl alcohol to aldehyde in water has been achieved by using home-prepared uncalcined brookite TiO(2). Three different lamp irradiances have been applied in order to check the influence ... -
Determination of Photoadsorption Capacity of Polychrystalline TiO2 Catalyst in Irradiated Slurry
(Elsevier Academic Press Inc, 2009)… -
Selective separation of uranium containing glutamic acid molecular-imprinted polymeric microbeads
(Marcel Dekker Inc, 2003)… -
Graphite-supported TiO2 for 4-nitrophenol degradation in a photoelectrocatalytic reactor
(Elsevier Science Sa, 2009)Amorphous TiO2, prepared at room temperature through a sol-gel method implementing hydrolysis of TiCl4, has been supported on graphite rods and then annealed at 673 K. In this way graphite was completely covered by a porous ... -
Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature
(Royal Soc Chemistry, 2009)Home-prepared (HP) rutile TiO2 catalysts were prepared at room temperature by using H2O and TiCl4 in different ratios and without addition of additives. The catalysts were used for carrying out the selective photocatalytic ... -
Photodegradation of pharmaceutical drugs in aqueous TiO2 suspensions: Mechanism and kinetics
(Elsevier Science BV, 2007)The degradation and mineralization of Tamoxifen (TAM) and Gemfibrozil (GEM) drugs, whose molecular structures exhibit ethereal bonds, have been carried out by irradiating aqueous suspensions of TiO2 with near-UV light at ... -
Nanostructured rutile TiO2 for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water
(American Chemical Society, 2008)Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, ...