Güncel Gönderiler: Fen Fakültesi
Toplam kayıt 2379, listelenen: 1401-1420
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Determination of paracetamol based on electropolymerized-molecularly imprinted polypyrrole modified pencil graphite electrode
(Elsevier Science Sa, 2007)Preparation of a molecularly imprinted polymer (MIP) film and its recognition property for paracetamol are investigated. The polypyrrole (PPy) film was prepared by the cyclic voltammetric deposition of pyrrole (Py) in the ... -
Synthesis and catalytic activity of perfluoroalkylated pyridine-palladium(II) complex toward olefin hydrogenation in scCO(2) and conventional organic solvents
(Elsevier Science BV, 2006)The perfluoroalkylated pyridine, (o-COOCH2(CF2)7CF(3)-NC5H4), has been synthesized in two step from nicotinic acid and then the title compound, [Pd(o-COOCH2,-(CF2)(7)CF3-NC5H4)(2)(OAc)(2)], obtained by reaction with ... -
Oxidation of 2,6-di-tert-butylphenol with tert-butyl hydroperoxide catalyzed by iron phthalocyanine tetrasulfonate in a methanol-water mixture
(Elsevier Science BV, 2007)The oxidation of 2,6-di-tert-butylphenol (DTBP) with tert-butyl hydroperoxide (Bu'OOH) catalyzed by iron phthalocyanine tetrasulfonate ([FePcTS]) in a 8-to-1 methanol-water mixture resulted with about 70-80% conversion of ... -
Phosphorus-nitrogen compounds: Synthesis and spectral investigations on new spiro-cyclic phosphazene derivatives
(Pergamon-Elsevier Science LTD, 2007)The condensation reaction of {N-[(2-hydroxyphenylmethyl)amino]-4,6-dimethylpyridine} (2), which is a reduction product of 1, with trimer N3P3Cl6 affords partially a substituted spiro-cyclic phosphazene derivative (3). The ... -
Solubility of an acid dye in supercritical carbon dioxide by ion-pairing with dodecyltrimethylammonium bromide
(Elsevier Science BV, 2006)In this study, solubility of Acid Red 57 (AR57), which is an anionic dye, in supercritical CO2 was investigated using an ion-pairing with dodecyltrimethylammonium (DTMA) bromide. The measurements of AR57 and AR57-DTMA in ... -
Adsorption of Acid Blue 193 from aqueous solutions onto BTMA-bentonite
(Elsevier Science BV, 2005)The adsorption of Acid Blue 193 (AB193) onto benzyltrimethylammonium (BTMA)-bentonite was investigated in aqueous solution in a batch system with respect to contact time, pH and temperature. The surface modification of ... -
Acidity study on some pyridazines
(Elsevier Science BV, 2004)The tautomeric, conformational equilibrium positions, and pK(a) values of some pyridazine derivatives 1-17 have been examined by means of semi empirical AM1 COSMO calculations in aqueous solution (epsilon=78.4). The results ... -
Oxidation of 2,6-di-tert-butylphenol with tert-butylhydroperoxide catalyzed by cobalt(II) phthalocyanine tetrasulfonate in a methanol-water mixture and formation of an unusual product 4,4 '-dihydroxy-3,3 ',5,5 '-tetra-tert-butylbiphenyl
(Elsevier Science BV, 2005)The oxidation of 2,6-di-tert-butylphenol (DTBP) with tert-butylhydroperoxide (Bu'OOH) catalyzed by cobalt(II) phthalocyanine tetrasulfonate ([CoPcTS](4-)) in a 4:1 methanol-water mixture gave predominantly the coupled ... -
Measurement and correlation of solubility of Acid Red 57 in supercritical carbon dioxide by ion-pairing with hexadecyltrimethylammonium bromide
(Elsevier Science BV, 2006)Solubility of C.I. Acid Red 57 (AR57) in supercritical carbon dioxide was measured by ion-pairing with hexadecyltrimethylammonium (HDTMA) bromide. The solubility measurements of AR57 and AR57-HDTMA in supercritical carbon ... -
Comparison of supercritical fluid and Soxhlet extractions for the quantification of hydrocarbons from Euphorbia macroclada
(Elsevier Science BV, 2004)This study compares conventional Soxhlet extraction and analytical scale supercritical fluid extraction (SFE) for their yields in extracting of hydrocarbons from arid-land plant Euphorbia macroclada. The plant material was ... -
Effect of indium incorporation on the optical properties of spray pyrolyzed Cd0.22Zn0.78S thin films
(Inst Physics Acad Sci Czech Republic, 2006)In this study, effect of indium incorporation on the optical properties is investigated for the spray pyrolyzed onto glass substrates at 275 degrees C substrate temperature undoped and indium doped Cd0.22Zn0.78S thin films. ... -
Effect of exchange-correlation potential on the plasmon dispersions in a doped symmetrical double quantum well
(Wiley-V C H Verlag GMBH, 2007)We have calculated the plasmon dispersion relations in a doped double quantum well with and without exchange-correlation potential added to the effective potential of the system. The calculations were done for high and low ... -
Validated capillary electrophoresis study for the determination of cetirizine in pharmaceutical forms
(Taylor & Francis Inc, 2006)A capillary electrophoretic method for the determination of cetirizine is described in this study. The method was developed by using a running buffer consisting of 10 mM of 10% methanol with pH 8.5, employing a fused silica ... -
2,2 ',3,4-Tetrahydroxy-3 '-sulpho-5 '-nitroazobenzene for spectrophotometric determination of aluminium in pharmaceutical suspensions and granite
(Elsevier Science BV, 2005)A selective and sensitive new spectrophotometric method has been developed for the determination of aluminium.2,2',3,4-Tetrahydroxyy-3'-sulpho-5'-nitroaobenzene (tetrahydroxyazon SN) formed an orange chelate with aluminium ... -
A study on the pyrazoles: tautomerism, conformation, acidity, and basicity by means of AM1 semiempirical method in the gas and aqueous solution
(Elsevier Science BV, 1999)A comprehensive theoretical study of some pyrazolones and their fixed model compounds is presented. The tautomeric equilibrium and acidity constants of these compounds have been investigated both in the gas and aqueous ... -
Negative mass solitons in gravity
(American Physical Soc, 2006)We first reconstruct the conserved (Abbott-Deser) charges in the spin-connection formalism of gravity for asymptotically (Anti)-de Sitter spaces, and then compute the masses of the AdS soliton and the recently found ... -
Adsorption behavior of a disperse dye on polyester in supercritical carbon dioxide
(Elsevier Science BV, 2005)In order to understand the adsorption behavior of the dyeing of polyester fibres in supercritical carbon dioxide at 95 degrees C and 300 bar, the rate of dyeing and the equilibrium adsorption of a disperse dye, C.I. Disperse ... -
Gravitational charges of transverse asymptotically AdS spacetimes
(American Physical Soc, 2006)Using Killing-Yano symmetries, we construct conserved charges of spacetimes that asymptotically approach to the flat or anti-de Sitter spaces only in certain directions. In D dimensions, this allows one to define gravitational ... -
Biomimetic catalysis of an organophosphate by molecularly surface imprinted polymers
(Elsevier Science BV, 2005)A synthetic polymer selective for paraoxon was prepared by a molecular surface imprinting technique. We have combined molecular imprinting with the ability of histidine to chelate metal ions to create active centrum of ... -
Intersubband electron transition across a staircase potential containing quantum wells: light emission
(Academic Press LTD Elsevier Science LTD, 2005)We present a theoretical investigation of a novel staircase-like light emitter based on the GaAs/GaxAl1-xAs material system. The emission wavelength is around 12 mum. The device operation is based on the intersubband ...