Güncel Gönderiler: Kimya Bölümü
Toplam kayıt 107, listelenen: 61-80
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Crystal structure of 2-[2-(2-aminophenoxy)ethoxy]-N-[(1E)-2,3,5,6,8,9,11,12-octahydro-1,4,7,1 0,13-benzopentaoxacyclopentadecin-15-ylmethylene]aniline
(Japan Society for Analytical Chemistry, 2006)The title compound, C29H34N2O7, is a substituted monotopic benzo-15-crown-5-ether ligand. It belongs to the space group P21/a with cell parameters a = 8.9857(6), b = 25.0353(17), c = 12.6979(9)Å and ß = 109.730(1)o. The ... -
Separation of catechins and methylxanthines in tea samples by capillary electrochromatography
(2009)In this paper, the simultaneous separation of several polyphenols such as (+)-catechin, (-)-epicatechin, (-)-epigallocatechin, theophylline, caffeine in green and black teas by capillary electrochromatography (CEC) was ... -
The synthesis, characterization and structural analysis of a Co(III) complex of 1,10-phenanthroline and perfluorosebacic acid, [Co(HL)(phen) 2(H2O)]L·H2O
(Verlag der Zeitschrift fur Naturforschung, 2006)The hexacoordinated mononuclear Co(III) complex 1, [Co(HL)(phen) 2(H2O)]L·H2O, with the mixed ligands (H2L = HO2C(CF2)8CO2H and 1,10-phenantroline) has been synthesized and characterized by elemental analysis, IR and UV/vis ... -
Selective solid-phase extraction of Cd(II) using double imprinting strategy
(2010)Molecular imprinting technology is a strategy for producing chemically selective binding sites, which recognize a particular molecule, in a macroporous polymer matrix. Molecular recognition-based separation techniques have ... -
Evaluation of polymer-supported rhodium catalysts in 1-octene hydroformylation in supercritical carbon dioxide
(American Chemical Society, 2003)Supercritical CO2 has been used as a benign solvent in the hydroformylation of 1-octene using a Rh-based catalyst. The catalyst is attached to a polymer backbone that has fluoroacrylate branches that make it soluble in ... -
Reverse atom transfer radical polymerization of stearyl methacrylate using 2,2'-azobisisobutyronitrile as the initiator
(2002)The living/controlled radical polymerization of stearyl methacrylate was carried out with a conventional radical initiator (2,2'-azobisisobutyronitrile) in N,N-dimethylformamide in the presence of a 2,2'-bipyridine complex ... -
Amino acid conjugated self assembly molecules modified Si wafers [Amino asit konjuge kendili?inden düzenlenen moleküller ile si pulcuklari{dotless}n modifikasyonu]
(Institute of Electrical and Electronics Engineers Inc., 2003)In this study, Si wafer surface was modified with newly synthesized self-assembled monolayers to mimic a biocompatible micro-environment for the cells and to observe their behavior. Begin with; Si wafer is chosen as its ... -
Structural studies of water-soluble ß-brominated manganese porphyrins: Stabilities of MnTDCSPPBr8 and MnTSPPBr8 as homogeneous and supported reagents toward hydrogen peroxide and sodium hypochlorite
(2001)This article describes the structural stabilities of [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(2,6-dichloro-3- sulfonatophenyl)porphinato]manganese(III) X (where X = H2O and/or OH-, depending on pH) (MnTDCSPPBr8) ... -
Protonation, tautomerization and valence tautomerization of selected imidazo[4,5-f]quinolines. A theoretical study of gas and liquid basicity of imidazo[4,5-f]quinolines
(1993)The theoretical calculations on imidazo[4,5-f] quinolines has shown that the first protonation takes place at the pyridine, nitrogen atom rather than at the imidazole nitrogen atom. The preferred tautomeric form was found ... -
Latex supported manganese (III) porphyrin catalysts for oxidations of alkenes by hydrogen peroxide and tert-butyl hydroperoxide in the aqueous medium
(1996)Cationic polymer latexes were prepared by emulsion copolymerization of vinylbenzyl chloride and divinylbenzene followed by quaternization with trimethylamine and used as catalyst supports for 5,10,15,20-tetrakis(2, ... -
Performance of dye-affinity beads for aluminium removal in magnetically stabilized fluidized bed
(2004)Background: Aluminum has recently been recognized as a causative agent in dialysis encephalopathy, osteodystrophy, and microcytic anemia occurring in patients with chronic renal failure who undergo long-term hemodialysis. ... -
Photocatalytic oxidation of nitrobenzene and phenylamine: Pathways and kinetics
(John Wiley & Sons Inc, 2007)The oxidation of nitrobenzene and phenylamine has been carried out by heterogeneous photocatalysis in aqueous suspensions of commercial TiO2. The photoreactivity results indicate that two reaction pathways occur in parallel ... -
Photocatalytic selective oxidation of 4-methoxybenzyl alcohol to aldehyde in aqueous suspension of home-prepared titanium dioxide catalyst
(Wiley-V C H Verlag GMBH, 2007)The photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde (PAA) was performed in water with organic-free suspensions of home-prepared and commercial titanium dioxide (TiO2) catalysts. The nanostructured ... -
Kinetics of 4-Methoxybenzyl Alcohol Oxidation in Aqueous Solution in a Fixed Bed Photocatalytic Reactor
(American Chemical Society, 2010)The photocatalytic oxidation of 4-methoxybenzyl alcohol in water was performed in a fixed bed continuous annular reactor by using a home-prepared TiO2 catalyst supported on Pyrex glass beads. The investigation was aimed ... -
Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home prepared titanium dioxide 2. Intrinsic and surface features of catalysts
(Elsevier Science BV, 2008)In this paper some intrinsic electronic properties of home prepared (HP) TiO2 Catalysts were investigated by diffuse reflectance spectroscopy and quasi-Fermi level measurements. These powders were used for carrying out the ... -
Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home-prepared titanium dioxide 1. Selectivity enhancement by aliphatic alcohols
(Elsevier Science BV, 2008)Oxygenated aqueous suspensions of home-prepared (HP) and commercial TiO2 catalysts were used in a batch photoreactor for carrying out the oxidation of benzyl alcohol (BA) and 4-methoxybenzyl alcohol (MBA) under different ... -
Self-assembled titania-silica-sepiolite based nanocomposites for water decontamination
(Royal Soc Chemistry, 2009)This work describes the preparation of microchannel structured monolithic pieces by the "ice-segregation induced self-assembly'' (ISISA) process. The monoliths exhibit a hierarchical structure composed of homogeneously ... -
Home-prepared anatase, rutile, and brookite TiO2 for selective photocatalytic oxidation of 4-methoxybenzyl alcohol in water: reactivity and ATR-FTIR study
(Royal Soc Chemistry, 2009)TiO2 catalysts of anatase, rutile and brookite phase were prepared at low temperature and tested for carrying out the photocatalytic partial oxidation of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde (p-anisaldehyde) ... -
A quantitative method of photoadsorption determination for irradiated catalyst in liquid-solid system
(Elsevier Science BV, 2009)A method for determining the amount of substrate adsorbed onto the catalyst surface in liquid-solid photocatalytic system under reaction conditions (photoadsorption) is proposed. The method has been applied to the ... -
Environmentally Friendly Photocatalytic Oxidation of Aromatic Alcohol to Aldehyde in Aqueous Suspension of Brookite TiO(2)
(Springer, 2008)Photocatalytic oxidation of 4-methoxybenzyl alcohol to aldehyde in water has been achieved by using home-prepared uncalcined brookite TiO(2). Three different lamp irradiances have been applied in order to check the influence ...