Gelişmiş Arama

Basit öğe kaydını göster

dc.contributor.authorSay, Rıdvan
dc.contributor.authorGaripcan, B
dc.contributor.authorEmir, S
dc.contributor.authorPatir, S
dc.contributor.authorDenizli, Adil
dc.date.accessioned2019-10-20T09:30:47Z
dc.date.available2019-10-20T09:30:47Z
dc.date.issued2002
dc.identifier.issn0927-7757
dc.identifier.urihttps://dx.doi.org/10.1016/S0927-7757(01)00891-3
dc.identifier.urihttps://hdl.handle.net/11421/17459
dc.descriptionWOS: 000173356400010en_US
dc.description.abstractDifferent metal-complexing ligands carrying synthetic adsorbents have been reported in the literature for heavy metal removal. We have developed a novel and new approach to obtain high metal adsorption capacity utilizing 2-methacrylamidohistidine (MAH) as a metal-complexing ligand. MAH was synthesized by using methacrylochloride and histidine. Spherical beads with an average size of 150-200 mum were obtained by the radical suspension polymerization of MAH and 2-hydroxyethylmethacrylate (HEMA) conducted in an aqueous dispersion medium. Owing to the reasonably rough character of the bead surface, p(HEMA-co-MAH) beads had a specific surface area of 17.6 m(2) g(-1). Synthesized MAH monomer was characterized by NMR. p(HEMA-co-MAH) beads were characterized by swelling studies, FTIR and elemental analysis. These p(HEMA-co-MAH) affinity beads with a swelling ratio of 65%, and containing 1.6 mmol MAH g(-1) were used in the adsorption/desorption of copper(II) ions from metal solutions. Adsorption equilibria was achieved in similar to 2 h. The maximum adsorption of Cu(II) ions onto pHEMA was similar to 0.36 mg Cu(II) g(-1). The MAH incorporation significantly increased the Cu(II) adsorption capacity by chelate formation of Cu(II) ions with MAH molecules (122.7 mg Cu(II) g(-1)), which was observed at pH 7.0. pH significantly affected the adsorption capacity of MAH incorporated beads. The observed adsorption order under non-competitive conditions was Cu(II) > Cr(III) > Hg(II) > Pb(II) > Cd(II) in molar basis. The chelating beads can be easily regenerated by 0.1 M HNO(3) with higher effectiveness. These features make p(HEMA-co-MAH) beads very good candidate for Cu(II) removal at high adsorption capacityen_US
dc.language.isoengen_US
dc.publisherElsevier Science BVen_US
dc.relation.isversionof10.1016/S0927-7757(01)00891-3en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMethacrylamidohistidineen_US
dc.subjectAffinity Beadsen_US
dc.subjectAminoacid-Ligandsen_US
dc.subjectCopper(Ii) Removalen_US
dc.titlePreparation of poly(hydroxyethyl methacrylate-co-methacrylamidohistidine) beads and its design as a affinity adsorbent for Cu(II) removal from aqueous solutionsen_US
dc.typearticleen_US
dc.relation.journalColloids and Surfaces A-Physicochemical and Engineering Aspectsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume196en_US
dc.identifier.issue2.Maren_US
dc.identifier.startpage199en_US
dc.identifier.endpage207en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorSay, Rıdvan


Bu öğenin dosyaları:

Thumbnail

Bu öğe aşağıdaki koleksiyon(lar)da görünmektedir.

Basit öğe kaydını göster