dc.contributor.author | Hökelek, Tuncer | |
dc.contributor.author | Süzen, Yasemin | |
dc.contributor.author | Tercan, Barış | |
dc.contributor.author | Aybirdi, Özgür | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.date.accessioned | 2019-10-20T09:14:01Z | |
dc.date.available | 2019-10-20T09:14:01Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.uri | https://dx.doi.org/10.1107/S1600536809030098 | |
dc.identifier.uri | https://hdl.handle.net/11421/17131 | |
dc.description | WOS: 000268510800143 | en_US |
dc.description | PubMed ID: 21583312 | en_US |
dc.description.abstract | The centrosymmetric title Ni-II complex, [Ni(C9H10NO2)(2)-(C10H14N2O)(2)(H2O)(2)], contains two dimethylaminobenzoate (DMAB), two diethylnicotinamide (DENA) ligands and two water molecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni-II atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni-II atom is displaced by 0.681 (1) angstrom out of the least-squares plane of the carboxylate group. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.61 (7)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)degrees. An intramolecular O-H center dot center dot center dot O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link molecules into a three-dimensional network. Two weak C-H center dot center dot center dot pi interactions are also present. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Int Union Crystallography | en_US |
dc.relation.isversionof | 10.1107/S1600536809030098 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.title | Diaquabis(N,N-diethylnicotinamide-kappa N-1)bis[4-(dimethylamino)benzoato-kappa O]nickel(II) | en_US |
dc.type | article | en_US |
dc.relation.journal | Acta Crystallographica Section E-Crystallographic Communications | en_US |
dc.contributor.department | Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü | en_US |
dc.identifier.volume | 65 | en_US |
dc.identifier.startpage | M1015 | en_US |
dc.identifier.endpage | U1746 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.contributor.institutionauthor | Süzen, Yasemin | |