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dc.contributor.authorSemerci, Fatih
dc.contributor.authorYeşilel, Okan Zafer
dc.contributor.authorSoylu, Mustafa Serkan
dc.contributor.authorYerli, Yusuf
dc.contributor.authorDal, Hakan
dc.date.accessioned2019-10-20T09:03:23Z
dc.date.available2019-10-20T09:03:23Z
dc.date.issued2014
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.urihttps://dx.doi.org/10.1016/j.jssc.2013.11.028
dc.identifier.urihttps://hdl.handle.net/11421/16700
dc.descriptionWOS: 000330081900034en_US
dc.description.abstractTwo new K+/Cu(II) and Zn(II) coordination polymers with pyridine-2,3-dicarboxylate (pydc), {K-2[Cu(mu-PYdc)(2)] center dot 3H(2)O}(n) (1) and {[Zn(mu-pydc)(H2O)(4-mim)] center dot H2O}(n) (2) (4-mim=4-methylimidazole) have been synthesized from zerovalent metal and characterized by IR, EPR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. In the sandwiched 3D anionic framework of 1, pydc ligands exhibit hexadentate coordination; tridentate coordination bond with Cu(II) and tridentate ionic interaction with K+ ions. {K2[Cu(mu-pydc)(2)] center dot 3H(2)O}(n) shows a rare topology consists of three dimensional (3,4,5)-connected network with the point symbol of {4(2).6}(2){4(2).8(4)}{4(3).6.8(6)}(2). The distorted square pyramidal geometry of 2 is completed with an nitrogen atom from 4-mim and aqua ligand to form a 1D polynuclear structure. The hydrogen bonds link the 1D chains into 3D architecture. The temperature dependent magnetic property of complex 1 has been studied. Complex 2 exhibits unusual yellow luminescence in the solid state at room temperatureen_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [109T201]en_US
dc.description.sponsorshipThis work has been supported by the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 109T201). The authors thank Mr. Mursel Arici for helpful discussions during the course of this work.en_US
dc.language.isoengen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.relation.isversionof10.1016/j.jssc.2013.11.028en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHeterometallic Coordination Polymersen_US
dc.subjectZero Valent Metal Precursoren_US
dc.subjectPyridine-2,3-Dicarboxylate Complexesen_US
dc.subjectEpren_US
dc.subjectLuminesanceen_US
dc.titleTwo new pyridine-2,3-dicarboxylate coordination polymers prepared from zerovalent metal precursor: Syntheses, luminescent and magnetic propertiesen_US
dc.typearticleen_US
dc.relation.journalJournal of Solid State Chemistryen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume210en_US
dc.identifier.issue1en_US
dc.identifier.startpage224en_US
dc.identifier.endpage231en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorDal, Hakan


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