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Phosphorus-nitrogen compounds. Part 29. Syntheses, crystal structures, spectroscopic and stereogenic properties, electrochemical investigations, antituberculosis, antimicrobial and cytotoxic activities and DNA interactions of ansa-spiro-ansa cyclotetraphosphazenes
Elmas, Gamze; Okumuş, Aytuğ; Koç, L. Yasemin; Soltanzade, Hossien; Kılıç, Zeynel; Hökelek, Tuncer; Yavuz, Makbule (Elsevier France-Editions Scientifiques Medicales Elsevier, 2014)A number of novel ansa-spiro-ansa (asa) cyclotetraphosphazenes (1a-5b) was prepared in the range of 63-90% yields. The structures of the compounds were verified by MS, FTIR, H-1, C-13{H-1} and P-31{H-1} NMR, heteronuclear ... -
Phosphorus-nitrogen compounds: Part 31. Syntheses, structural and stereogenic properties, in vitro cytotoxic and antimicrobial activities, and DNA interactions of bicyclotetraphosphazenes containing bulky side group
Mutlu, Gurcu; Elmas, Gamze; Kılıç, Zeynel; Hökelek, Tuncer; Koç, L. Yasemin; Türk, Mustafa; Dal, Hakan (Elsevier Science Sa, 2015)Hexachlorocyclotriphosphazene, N3P3Cl6, and octachlorocyclotetraphosphazene, N4P4Cl8, were reacted with K2N2O2 salt of symmetric tetradentate ligand to obtain spiro-bino-spiro [(sbs) (2)] and 2,6-spiro-ansa-spiro [(2,6-sas) ...